What is the reactivity order of Aryl Halides in a substitution reaction? 1. Ar-F>Ar-Br>Ar-I>Ar-Cl...

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What is the reactivity order of Aryl Halides in a substitution reaction? {eq}1. Ar-F > Ar-Br > Ar-I > Ar-Cl \\ 2.Ar-I > Ar-Br > Ar-Cl > Ar-F \\ 3. Ar-F > Ar-Cl > Ar-Br > Ar-I \\ 4.Ar-I > Ar-Br > Ar-F > Ar-Cl {/eq}

Reactivity of Aryl Halides in a Substitution Reaction

Substitution reaction is a type of reaction where one of the groups in the substrate gets replaced by an incoming group introduced into the medium.

It can be either nucleophilic (attacked by a nucleophile) or electrophilic (attacked by an electrophile). Also, the mechanism via which the reaction occurs can be different depending on a lot of factors like substrate used, reagent used, the solvent medium.

Thus, the reactivity of all substrates are not equal but vary according to their nature for a fixed reagent and solvent medium.

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Substitution reactions may proceed via two pathways - {eq}\rm S_N1{/eq} and {eq}S_N2 {/eq}

  • {eq}\rm S_N1 {/eq} involves two steps where the former...

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Substitution Reaction | Types & Examples

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Chapter 10 / Lesson 23
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Learn about substitution reactions in organic chemistry. Understand what a substitution reaction is, explore its two types, and see an example of both types.


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