Part A Barium sulfate, BaSO4, is used in medical imaging of the gastrointestinal tract because it...
Question:
Part A Barium sulfate, BaSO4, is used in medical imaging of the gastrointestinal tract because it is opaque to X rays. A barium sulfate solution, sometimes called a cocktail, is ingested by the patient, whose stomach and intestines can then be visualized via X-ray imaging. If a patient ingests 280 mL of a saturated barium sulfate solution, how much toxic Ba2+ ion has the patient consumed?
The solubility product Ksp of BaSO4 is 1.10* 10-10.
Express your answer to three significant figures and include the appropriate units.
Part B
There are some data that suggest that zinc lozenges can significantly shorten the duration of a cold. If the solubility of zinc acetate, Zn(CH3COO)2, is 43.0 g/L, what is the solubility product Ksp of this compound?
Express your answer numerically.
Solubility and Solubility Product Constant:
A sparingly soluble salt M{eq}_y {/eq}N{eq}_x {/eq} is in equilibrium with its ions in a saturated solution. The solubility of this sparingly soluble salt is represented by the equation below:
{eq}M_yN_x(s) \rightleftharpoons yM^{x+}(aq)+xN^{y-} {/eq}
The equilibrium constant associated with this solubility equation is called the Solubility Product Constant, Ksp. It is equal to the product of the concentration of the ions raised to their individual coefficient in the balanced reaction. Ksp can also be represented by the molar solubility of the sparingly soluble salt in which the molar solubility s is equal to the equilibrium concentration of the ion divided by the coefficient of the ion, or the equilibrium concentration of the ion is equal to the product of the molar solubility and the coefficient of the ion in the balanced equation.
{eq}Ksp=[M^{x+} ]^{y}[N^{y-} ]^{x}=(y*s)^{y}(x*s)^{x} {/eq}
Answer and Explanation: 1
Become a Study.com member to unlock this answer! Create your account
View this answer
Part A
Barium sulfate, BaSO{eq}_4 {/eq}, is used in medical imaging of the gastrointestinal tract because it is opaque to X rays. A barium...
See full answer below.
Ask a question
Our experts can answer your tough homework and study questions.
Ask a question Ask a questionSearch Answers
Learn more about this topic:

from
Chapter 11 / Lesson 5Learn about solubility product constant. Understand the definition of Ksp, the Ksp formula, how to calculate Ksp, and how to find molar solubility from Ksp.
Related to this Question
- Barium sulfate is used in medical imaging of the gastrointestinal tract because it is opaque to X-rays. A barium sulfate solution, sometimes called a cocktail, is ingested by the patient, whose stomach and intestines can then be visualized via X-ray imagi
- Barium sulfate, BaSO_4, is used in medical imaging of the gastrointestinal tract because it is opaque to X-rays. A barium sulfate solution, sometimes called a cocktail, is ingested by the patient, whose stomach and intestines can then be visualized via X-
- In medicine, barium sulfate (BaSO4) is used as a tracer in the procedure for gastrointestinal x-rays, even though the barium ion (Ba2+) is toxic to humans. Given the reaction, BaSO4(s) rightleftharpoons Ba2+ (aq) + SO42- (aq), what must be true about the
- In medicine, barium sulfate (BaSO4) is used as a tracer in the procedure for gastrointestinal x-rays, even though the barium ion (Ba2+) is toxic to humans. Given the reaction: BaSO4(s) \leftrightharpoons Ba2+ (aq) + SO42- (aq), what must be true about th
- Barium sulfate is used as a radio-opaque material for patients receiving CAT scans and upper GI series. Barium ion is highly toxic. Reconcile these two statements.
- Prior to having an X-ray exam of the upper gastrointestinal tract, a patient drinks an aqueous suspension of solid BaSO4. Scattering of X-rays by barium greatly enhances the quality of the photograph. Although Ba2+ is toxic, ingestion of BaSO4 is safe bec
- Barium sulfate is used to produce distinct X-rays of the gastrointestinal tract. What is the maximum mass of barium sulfate that can dissolve in 5.00 liters of water (a volume much greater than that of the average gastrointestinal tract)?
- A solution contains 45 mg/L Ba^2+. A consultant has suggested that the Ba^2+ could be removed from solution by converting it to solid barium sulfate [BaSO_4(s)]. To accomplish this, she proposes addin
- You were told to add the barium chloride reagent to your sulfate sample slowly, and to heat the samples for several minutes to allow the precipitate of barium sulfate to digest. These procedures were intended to prevent the barium sulfate precipitate from
- Patients undergoing an upper gastrointestinal tract laboratory test are typically given an X-ray contrast agent that aids with the radiologic imaging of the anatomy. One such contrast agent is sodium diatrizoate, a non-volatile water-soluble compound.
- Barium and all of its compounds are very toxic. For example, the estimated fatal dose of barium chloride (BaCl2, solubility 375 g/L) is about 1 gram for a 70-kg human. Yet the barium contrast agent used in abdominal studies contains 450 grams of barium su
- Magnesium displaces copper from a dilute solution of copper(II) sulfate; the pure copper will settle out of the solution. A copper(II) sulfate solution is mixed by dissolving 25.000 g of copper(II) sulfate, and then it is treated with an excess of magnesi
- Barium phosphate is a very finely divided precipitate. Identify two special steps in the procedure that are incorporated into the experiment that minimize the loss of barium phosphate in its analysis.
- Saccharin (C7H5NO3S) is sometimes dispensed in tablet form. Ten tablets with a total mass of 0.5894 g were dissolved in water. This solution was then oxidized to convert all the sulfur to sulfate ion, which was precipitated by adding an excess of barium
- If ordinary filter paper, instead of ashless paper were used, how would your experiemental results on Sulfate analysis be affected? would they be too high or too low? why are the washes of the barium
- Iron(II) Sulfate forms a blue-green hydrate with the formula FeSO4 �n H2O(s). If this hydrate is heated to a high enough temperature, H2O(g) can be driven off, leaving the pale yellow anhydrous salt F
- Iron(II) Sulfate forms a blue-green hydrate with the formula FeSO_4 * H_2O(s). If this hydrate is heated to a high enough temperature, H_2O(g) can be driven off, leaving the dirty yellow anhydrous salt FeSO_4(s). An 18.300-g sample of the hydrate was heat
- Ten drops of water are added to two small test tubes and to each is added one drop of iodine. The solution turns from a lighter yellow to a darker orange. To one of the test tubes some powdered magnesium is added and mixed well and centrifuged.
- Epsom salt is chemically known as A. copper sulphate B. magnesium sulphate C. ferrous sulphate D. copper sulphate
- Iron(II) Sulfate forms a blue-green hydrate with the formula FeSO4 n H2O(s). If this hydrate is heated to a high enough temperature, H2O(g) can be driven off, leaving the pale yellow anhydrous salt FeSO4(s). A 6.060-g sample of the hydrate was heated to
- An aqueous solution containing barium iodide (BaI_2) is electrolyzed in a cell containing inert electrodes. The products at the anode and cathode are: Ba (anode), I_2 (cathode), Ba (cathode), O_2 (anode), H_2 (anode), O_2 (cathode), H_2 (cathode) and I_2
- Aluminum sulfate, known as cake alum, has a remarkably wide range of uses, from dyeing leather and cloth to purifying sewage. In aqueous solution, it reacts with base to form a white precipitate. (a)
- 1. An unknown solution gave a strong yellow flame test. The solution gave no reaction with ammonium carbonate, ammonium phosphate, or ammonium sulfate. The halide test produced a yellow-orange color i
- There are two possible methods for recovering copper from a solution of copper(II) sulfate, one uses precipitation and the other uses redox. (a) Copper(II) ions can be precipitated as copper(II) carbo
- An unknown solution gives a brick red flame test with flashes of yellow. The unknown gives a white precipitate with ammonium carbonate and ammonium phosphate, but no reaction with ammonium sulfate. th
- How do we know if a reaction cocktail has been compromised? What must be done just before putting the centrifuge tubes into the centrifuge? Why do you add ground ammonium sulfate, and why do you add
- You start your experiment with an empty test tube having a mass of 10.3362 g. You are working with a hydrated compound of calcium sulfate. After adding the hydrate to the empty test tube, the mass of
- The sulfate ion concentration in natural water can be determined by measuring the turbidity that results when an excess of BaCl2 is added to a measured quantity of the sample. A turbidimeter, the instrument used for this analysis, was calibrated with a se
- we did a lab yesterday for gravimetric analysis of an unknown sulfate and for the calculations it is asking us to calculate the mass of sulfate in the unknown sample. I am not sure if this means to ba
- 4.Describe the procedure for preparing a liquid sample for infrared examination. 5. Although IR spectra of solids are most commonly run as KBr pellets, they are sometimes run as solutions. Even though
- A reddish-brown vessel developed a green-colored solid X when left open in air for a long time. When reacted with dil. H_2SO_4, it forms a blue-colored solution along with brisk effervescence due to colorless and odorless gas Z. X decomposes to form black
- A 1.150 g sample of the hydrated salt ZnSO_4. X H_2O is dissolved in water and the sulfate ion is precipitated by adding an excess of BaCl_2 solution. The mass of pure and dry BaSO_4 precipitated obtained is 0.9335 g. What is the formula of the zinc sulfa
- Student A performed gravimetric analysis for sulfate in her unknown using the same procedures we did. Results of her three trials were 68.6%, 66.2% and 67.1% sulfate. Student B analyzed the same unkno
- A student was assigned a colorless unknown. The student added five drops of 1.0 M barium chloride solution to 1.0 mL of the unknown solution. A white precipitate formed. In a second experiment, the student added two drops of 0.5 M NH3 solution to 1.0 mL o
- A mixture contained aluminum sulfate and sodium sulfate. A sample of the mixture weighing 3.458 g was dissolved in water and treated with sodium hydroxide solution to yield a precipitate. The precipitate was incinerated to yield 0.474 g aluminum oxide. a.
- In an analytical determination of arsenic, a solution containing arsenious acid, H3AsO3, potassium iodide, and a small amount of starch is electrolyzed. The electrolysis produces free iodine from iodide ion, and the iodine immediately oxidizes the arsenio
- A metal naphthenate sample, ashed and diluted to a fixed volume, gave an absorbance reading of 29. Two standard additions samples containing the same quantity of unknown solution plus 25 mg/ml and 50 mg/ml of barium gave readings of 53 and 78, respectivel
- In a dry evaporating dish, 7.50 g solid copper (II) sulfate pentahydrate was dissolved in 30.0 ml of deionized water at 60.0^\circ C. While stirring slowly 1.23 g of iron powder was added to the solution. The solution was allowed to sit for 10 minutes an
- Calculate the [OH-] of each aqueous solution with the following [H3O+]: Part A stomach acid, 1.5 x10^2M Part B urine, 6.0 x 10^6M Part C orange juice, 2.6 x 10^4M Part D bile, 7.5 x 10^9M
- 1 mL of 0.1 mol/L CuSO4 is mixed with a few drops of concentrated NH3. Then about 1 mL of 1 mol/L HCl is added to the solution. When performed in the lab, the solution went from a light blue to a solution that had a blue precipitate at the bottom, a dark
- Three colorless solutions in test tubes, with so labels, are in a test tube rack on the laboratory bench. Lying beside the test tubes are three labels potassium iodide K I ; silver nitrate, A g N O
- Three colorless solutions in test tubes, with no labels, are in a test tube rack on the laboratory bench. Lying beside the test tubes are three labels: A. potassium iodide, KI B. silver nitrate, A
- An unknown liquid (A) showed no IR absorption between 1500 and 2500 cm^{-1}. Similarly there was no absorption above 3000 cm^{-1}. Compound A reacted with alcoholic silver nitrate to give cloudiness after serval minutes and it also reacted with sodium iod
- Student A performed gravimetric analysis for sulfate in the unknown. Results of her three trials were 68.6%, 66.2%, and 67.1% sulfate. Student B analyzed the same unknown his results were 66.7%, 66.6%, and 66.5%. The unknown was sodium sulfate. Calculate
- A student mixes solutions of potassium iodide and lead nitrate in a test tube and notices that a yellow solid forms and settles to the bottom of the test tube. The student just performed a type of reaction.
- A cell was constructed with two lead electrodes. The electrolyte compartment is 1 M Pb(NO3)2(aq). In the other compartment, NaI has been added to a Pb(NO3)2 solution until a yellow precipitate forms a
- A sample of iron(II) sulfate was heated in an evacuated container to 920 K, where the following reactions occurred. Reaction (a): 2 FeSO_4(s) to Fe_2O_3(s) + SO_3(g) + SO_2(g). Reaction (b): SO_3(g) t
- The sulfate ion concentration in natural water can be founded by measuring the turbidity that results when an excess of BaCl2 is added to a measured quantity of the sample. A turbidimeter, the instrument used for this analysis, was calibrated with a serie
- An unknown sample produces a reddish precipitate upon reaction with 2,4-dinitrophenylhydrazine reagent, no color change with Schiff's reagent, and a yellow precipitate when mixed with iodine and base.
- Calcium oxalate (CaC2O4) is insoluble in water. For this reason it can be used to determine the amount of Ca^{2+} ions in fluids such as blood. The calcium oxalate isolated from blood is dissolved in acid and titrated against a standardized KMnO4 solution
- Three colorless solutions in test tubes, with no labels, are in a test tube rack on the laboratory bench. Lying beside the test tubes are three labels: -silver nitrate, AgNO_3 -hydrochloric acid, HCL -sodium carbonate, Na_2CO_3 You are to place the lab
- A student had difficulty decanting the supernatant solution from some test tubes, causing him to transfer some of the solid from the antacid tablet with the solution. Would this result in a high, low,
- You have a sample of a rat poison whose active ingredient is thallium(I) sulfate. You analyze this sample for the mass percentage of active ingredient by adding potassium iodide to precipitate yellow thallium(I) iodide. If the sample of rat poison weighed
- 3.05 g hydrated copper sulfate produces 1.94 g of anhydrous salt. Assuming complete removal of all water of crystallization, determine the formula of hydrated copper sulfate.
- Penicillin V was treated chemically to convert sulfur to barium sulfate, BaSO_4. An 8.19-mg sample of penicillin V gave 5.46 mg BaSO_4. a. What is the percentage of sulfur in penicillin V? b. If there is one sulfur atom in the molecule, what is the molecu
- The blue color of dextran blue solution is due to the well-known, blue complex formed between starches and iodine. If you only had the absorption spectrum of this solution, explain why its color could be predicted, based on the spectrum alone. In what par
- Dimethylnitrosamine (CH_3)_2N_2O is a carcinogenic (cancer-causing) substance that may be formed in foods, beverages, or gastric juices from the reaction of the nitrate ion (used as a food preservative) with other substances. What is the mass of 0.35 mol
- 1. Student A performed gravimetric analysis for sulfate in her unknown using the same procedures we did. Results of her 3 trials were 68.6%, 66.2%, 67.1% sulfate. Student B analyzed the same unknown h
- If you accidentally overheated the barium sulfate precipitate and the filter paper in the crucible, is it possible that BaO might be formed? How would this affect the results?
- Two solids (barium hydroxide octahydrate and ammonium thiocyanate) are mixed together in a flask, which is then set on a puddle of water on a wood block. A reaction occurs spontaneously, and the products form a liquid in the beaker and freeze the puddle o
- Saccharin (C7H5NO3S) is sometimes dispensed in tablet form. Ten tablets with a total mass of 0.5797 g were dissolved in water. The solution was then oxidized to convert all the sulfur to sulfate ion,
- A series of sulfate samples is to be analyzed by precipitation as BaSO_4. If it is known that the sulfate content in these samples ranges between 19% and 53
- When a 8.192 g sample of bluish-green crystals of hydrated nickel(II) sulfate is heated, all of the water of hydration is lost leaving 4.826 g of anhydrous nickel(II) sulfate. Write the formula of the hydrated crystal, showing the number of moles of water
- When a precipitate forms in gravimetric analysis, one must be concerned with contamination. Often this can happen when unwanted materials in the solution become involved with the precipitate. Adsorption and absorption are two processes that can bring this
- An 8.75-g sample of iron ore (mixture) is transformed to a solution of iron(II) sulfate, and this solution is titrated with 0.150 M K2Cr2O7 potassium dichromate. If it requires 67.8 mL of potassium dichromate solution to titrate the iron(II) sulfate solut
- The labels of bottles that contain barium hydroxide, hydrochloric acid and sodium carbonate had fallen off. When the contents of bottle A were mixed with B's contents, a white precipitate formed
- If you use a dirty buret, the titrant leaves drops of solution behind as the meniscus descends during delivery of the solution. The volume actually delivered by the buret will be the volume your readi
- After correctly preparing a Beer's law plot for the yellow food dye, a student read the percent transmittance of the unknown solution but neglected to zero the spectrophotometer with a water blank. Sh
- Saccharin (C7H5NO3S) is sometimes dispensed in tablet form. Ten tablets with a total mass of 0.5860 g were dissolved in water. They were oxidized to convert all the sulfur to sulfate ion, which was pr
- Copper(II) sulfate has been used extensively as a fungicide (kills fungus) and herbicide (kills plants). Copper(II) sulfate can be prepared in the laboratory by reaction of copper(II) oxide with sulfuric acid. f 2.49 g of copper(II) oxide is treated with
- An unknown solution gives a brick-red flame test. The solution produces a white precipitate with ammonium carbonate, ammonium sulfate, and ammonium phosphate after heating. Silver nitrate is added to
- A 1.317 g sample of a metal carbonate (MCO_3) was treated with 100.00 mL of .1083 M sulfuric acid (H_2SO_4), yielding CO_2 gas and an aqueous solution of the metal sulfate ((MS)_4). The solution was boiled to remove all the dissolved CO_2 and was then tit
- 3.05 g of hydrated copper sulfate produces 1.94 g of anhydrous salt. Assuming complete removal of water of crystallization, determine the formula of hydrated copper sulfate.
- A 3.05 g of hydrated copper sulfate produces 1.94 g of anhydrous salt. Assuming complete removal of all water of crystallization, determine the formula of hydrated copper sulfate.
- A few drops of water were added to a test tube containing 0.5 grams of anhydrous copper sulfate (CuSO4) and the following observations were noted. Anhydrous copper sulfate: light blue Anhydrous copper sulfate plus water: sky blue What can you conclude fro
- If phenolphthalein is used as an indicator for titrating Ca(OH)2 with titrant HCl instead of methyl orange, which is the recommended indicatory, would the reported solubility product for calcium hydroxide be too high, too low, or unaffected? Explain.
- When HCI + blue dye are mixed, does it produce a green mixture or green precipitate?
- 3. A student, following the procedure in this experiment, studied the response of red food dye to visible light and analyzed a stock solution of red food dye of unknown concentration. A series of dilu
- A student is asked to prepare 250.0 mL of 3.5 M copper (II) sulfate from solid copper (II) sulfate pentahydrate. Describe how this solution should be made in the chemistry laboratory.
- 2. A student added the following chemicals to a test tube and observed the color. Chemicals: An unknown containing one of the anions A¹⁻, B¹⁻ or C ¹⁻, a solution of C
- A solution may contain any of the Group III cations. Treatment of the solution with H_2O_2 in hot alkaline medium yields a yellow solution and a colored precipitate. Acidification of this solution fol
- A sample of water was observed to have a peculiar taste. The taste may be caused by chloride ions or sulphate ions. Design a flow chart to illustrate the procedure you can use to determine which ion is responsible for the taste. Identify each solution tha
- The active ingredient in Antabuse, a drug used for the treatment of chronic alcoholism, is tetraethylthiuram disulfide (296.54 g/mole). The sulfur in a 0.43210 g sample of an Antabuse preparation was oxidized to sulfur dioxide, which was absorbed in hydro
- A student used 5.06 g copper sulphate pentahydrate and salicyclic acid in the performance of the experiment. The student recovered 3.094 g of salicyclic acid and 2.146 g of copper sulphate pentahydrat
- Saccharin (C7H5NO3S) is sometimes dispensed in tablet form. Ten tablets with a total mass of 0.5800 g were dissolved in water. They were oxidized to convert all the sulfur to sulfate ion, which was pr
- A commercial sample of pyrite (FeS_2) is oxidized by bromine and nitric acid. The sulphate obtained is precipitated and heavy in the form of BaSO_4. If 0, 331 g of pyrite originated 0.813 g of BaSO_4,
- A 3.75-g sample of iron ore is transformed to a solution of iron(II) sulfate, FeSO4, and this solution is titrated with 0.150 M K2Cr2O7 (potassium dichromate). If it requires 43.7 mL of potassium dichromate solution to titrate the iron(II) sulfate solutio
- 10.0g of hydrated sodium sulphate decomposes to form 4.40g of anhydrous sodium sulfate on heating. Calculate formula mass of hydrated sodium sulphate and the value of x.
- Using ammonium sulfate, how could you separate the albumin from the globulin in egg whites?
- The mineral gypsum is a hydrate, with the formula CaSO_4.2H_2O. A sample of gypsum was heated until all the waters of hydration were driven off and the anhydrous calcium sulfate was obtained. After heating, the mass of calcium sulfate was 2.655 g. What wa
- A sample weighing 0.0123 g was dissolved in concentrated nitric acid to convert all of the arsenic to arsenate. The solution was diluted 10 times and excess silver added to precipitate silver arsenate (Ag_3 \cdot AsO_4), which was collected, dried, and we