An aqueous buffer solution at 25 degree C consists of 0.080 M chlorous acid (HClO_2) together...
Question:
An aqueous buffer solution at {eq}25^{\circ}C {/eq} consists of 0.080 M chlorous acid {eq}(HClO_2) {/eq} together with 0.040 M sodium chlorite ({eq}NaClO_2 {/eq}, the salt of the conjugate base of chlorous acid). The Ka of chlorous acid is {eq}1.0 \times 10^{-2} {/eq}. Calculate the pH of the solution.
Buffer System:
A buffer system is an aqueous solution designed to resist changes in its pH within a narrow range when small amounts of strong acid/base are added to it. This property is made possible through a weak acid-base conjugate pair, in which both the weak acid and weak base are present in comparable concentrations (i.e. numbers of moles). This represents a frozen equilibrium, where either component will experience minimal dissociation. Each conjugate pair will control the pH within a different narrow range and this property will be maintained as long as neither component of the buffer is fully exhausted (consumed).
Answer and Explanation: 1
Become a Study.com member to unlock this answer! Create your account
View this answer
This is a buffer system composed of chlorous acid (weak acid) and chlorite ion (conjugate weak base from sodium chlorite). The equilibrium of this...
See full answer below.
Ask a question
Our experts can answer your tough homework and study questions.
Ask a question Ask a questionSearch Answers
Learn more about this topic:
from
Chapter 11 / Lesson 8Learn how to calculate the pH of a buffer solution. Discover the purpose of a buffer solution, and work through examples using the buffer solution equation.
Related to this Question
- A buffer solution is prepared by dissolving 0.35 mol of NaF in 1.00 L of 0.53 M HF. Which of the following is true about the chemicals in the solution? a) NaF is the weak acid. b) F- is the conjugate acid. c) HF is the weak base. d) F- is the conjugate ba
- In an aqueous solution of Methylamine at pH 6, which component of the conjugate acid - base pair will have a higher concentration than the other? Explain the answer by: (a) writing the acid dissociation reaction (left to right) (b) the equilibrium constan
- What salt (sodium salt of the conjugate base) and acid (acetic acid or phosphoric acid) would be used to prepare a 0.1 M buffer for a pH of 4.5? Write the acid dissociation equation including the conjugate base.
- A buffer solution was prepared using the conjugate acid-base pair acetic acid and acetate ions. Write the chemical equations showing the reactions that take place when: (a) H^+ ions are added to the buffer solution. (b) OH^- ions are added to the buffer s
- A nitrous acid buffer solution contains 0.88 M nitrous acid (HNO_2) and 0.66 M of its conjugate base ((NO_2)^-). If a chemist adds 0.13 mol of hydroiodic acid (HI), a strong acid, to 0.50 L of the buffer solution, what will be the final pH of the solution
- What is the pH of a 0.0100 M ammonium formate solution? Ammonium ion is the conjugate acid of the weak base, ammonia with a Kb = 1.8 x 10^-5, and formate ion is the conjugate base of the weak acid fo
- Give the conjugate base of each acid: H3O+ H2Se HSO4- Give the conjugate acid of each base: Br- HPO42- CH3COO-
- The conjugate acid of ammonia is NH_4^+, a weak acid. If a 0.2 M NH_4Cl solution has a pH of 5.0, what is the K_a of NH_4^+?
- If a 0.100 M solution of a weak base is 2.34\% ionized, what are the K_b and pK_b for this base? What is the pK_a of its conjugate acid?
- Which solution below would have the greatest buffering capacity? Explain. The solution was prepared from a weak acid and the salt of its conjugate base. 0.172 M C6H5OHCOOH and 0.172 M C6H5OHCOONa, Ka = 1.05e-3 0.1347 M HOCH2COOH and 0.1347 M HOCH2COONa,
- A nitrous acid buffer solution contains 0.88 M nitrous acid (HNO2) and 0.66 M of its conjugate base (NO2). If a chemist adds 0.13 mol of hydroiodic acid (HI), a strong acid, to 0.50 L of the buffer solution, what will be the final pH of the solution? (
- 1) A weak acid has KA = 8.49 x 10^{-4}. What is the pKB of its conjugate base? 2) A weak base has KB = 9.49 x 10^{-3}. What is the pKB of this base? 3) Consider a weak acid "HA". What is the percent ionization of a 0.649 mol/L solution of HA? The KA of
- What is the pH of a solution that is 0.025 M in the weak base and 0.037 M in the conjugate weak acid (Ka = 7.1 x 10-6)?
- What is the pH of a solution that is 0.023 M in a weak base and 0.039 M in the conjugate weak acid? (Ka = 7.1 x 10-6)
- Given a 6 M solution of NH3 (Kb = 1.78 * 10-5) and 6 M HNO3: Part A: If a buffer were prepared, what species would be the acid in the buffer? The conjugate base? Write out an acid dissociation reacti
- You are handed a buffer solution that contains equal concentrations of a weak acid and its conjugate base. Not knowing the species in solution, what can you predict about the pH? (a) pH = 7.0, because the acid and base neutralize each other (b) pH < 7 b
- Which of the following acids (listed with Ka values) and their conjugate base would form a buffer with a pH of 2.34? a. HC_{7}H_{5}O_{2}, Ka = 6.5 x 10^{-5} b. HF, Ka = 3.5 x 10^{-4} c. HClO, Ka = 2.9 x 10^{-8} d. HCN, Ka = 4.9 x 10^{-10} e. HClO_{2}, Ka
- Which solution below would have the greatest buffering capacity? The solution was prepared from a weak acid and the salt of its conjugate base. 0.160 M C6H5OHCOOH and 0.160 M C6H5OHCOONa, Ka = 1.05e-3
- A buffer is prepared by dissolving 0.15 mol of a weak acid and 0.15 mol of its conjugate base salt in 1.00 L of water. The weak acid has a pK_a, of 5.2. Which of the following statements is/are correct? (1) The buffer has a pH of 5.2 (2) Dilution of the s
- Buffer solutions can be produced by mixing a weak acid with its conjugate base or by mixing a weak base with its conjugate acid. The Henderson-Hasselbalch equation pH = pKa + log(base)(acid) allows yo
- When a solution contains a weak acid and its conjugate base or a weak base and its conjugate acid, it will be a buffer solution. Buffers resist change in pH following the addition of acid or base. A b
- What is the pH of a solution which is .021 M in weak base and .035 M in the conjugate weak acid (Ka = 7.1 * 10^-6)?
- What is the pH of a solution which is 0.023 M in weak base and 0.039 M in the conjugate weak acid (Ka = 7.1 * 10-6)? ph=
- What is the pH of a solution which is 0.021 M in weak base and 0.037 M in the conjugate weak acid (Ka = 7.1 x 10^-6)?
- HNO2 is a weak acid (pKa = 3.15). Imagine that you want to prepare a pH = 3.15 buffer solution that contains the weak acid (HNO2) and its conjugate base (NO2-). Following is a list of chemicals that are available to you in the lab: H2O, HNO2, KNO2, HCl, a
- What is the pH of a buffer solution when the concentrations of both buffer components (the weak acid and its conjugate base) are equal? What happens to the pH when the buffer contains more of the weak acid than the conjugate base? More of the conjugate ba
- A solution of Na_2CO_3 has a pH of 10. The CO_3 ion is the conjugate base of the HCO_3^- ion. Write the net ionic equation for the reaction, which makes a solution Na_2CO_3 basic.
- The following buffer was prepared: 50. mL 2.0 M methylamine (CH3NH2) solution and 50. mL of 2.0 M methylamine hydrochloride (CH3NH3Cl) solution. The Kb for methylamine is 4.4 x 10-4. Part a) What is
- Which of the acids below will have the lowest pH in a 0.10 M solution of the acid? a. HClO b. HNO2 c. HSO4- d. HCO3-
- Chlorous acid, HClO_2, has an acid dissociation constant of 1.1 \times 10^{-2} \text{ at } 25^\circ C a) Write out the chemical reaction corresponding to this acid dissociation constant. b) A solution is prepared at 25^\circ C by adding 0.0300 mol of HCl
- Hydrofluoric acid (HF) is a highly toxic acid that is used in etching glass (K_a = 6.76 times 10^{-4}). What is the pH of a solution of a 0.137 M NaF, the conjugate base of HF?
- Write the chemical equation for H_2PO_4^- acid dissociation, identify its conjugate base and write the base dissociation chemical equation.
- Assuming your buffered solution contains acetic acid, HOAc, and the sodium salt of its conjugate base, NaOAc. Show the net ionic equations that occur when this buffered solution reacts with: (a) added
- Carbonic acid, H2CO3 is a weak acid. Its first Ka is 4.5 x 10-7. Calculate the Kb of its conjugate base.
- The pKa of the conjugate acid of sodium hydroxide (NaOH) is about 16 and the pKa of the conjugate acid of sodium bicarbonate (NaHCO_3) is about 6.4. Draw the structure of the molecule below after A.
- Write an equilibrium reaction for a buffer system made of the weak base, B, and its conjugate acid. If the buffer contains 1.05 M of B and 0.750M conjugate acid and has a pH of 9.50, what is the pH af
- The Ka values for several weak acids are given below. Which acid (and its conjugate base) would be the best buffer at pH 8.0? A. Formic acid: Ka = 1.8 x 10-4 B. Acetic acid: Ka = 1.8 x 10-5 C. HEPES:
- If the Ka of the conjugate acid is 1.40 x 10^-5, what is the pKb for the base?
- If the Ka of the conjugate acid is 5.53 x 10^-5, what is the pKb for the base?
- Carbonic acid is a weak acid in aqueous solution; Ka for the first acid ionization is equal to 4.2 x 10-7. Calculate pKb for the hydrogen carbonate ion HCO3-. a. 5.2 b. 8.9 c. 6.4 d. 4.2 e. 7.6
- 1. A student must make a buffer solution with a pH of 4.5. Determine which of the acids and conjugate listed below are the best options to make a buffer at the specified pH. **Weak Acids: ***a) phosphoric acid ***b) acetic acid ***c) formic acid ***d)
- A buffer contains a weak acid, HX, and its conjugate base, [{MathJax fullWidth='false' X^{-} }]. The weak acid has a pKa of 4.5, and the buffer solution has a pH of 4.3. Without doing a calculation, predict whether HX = X^{-} , HX greater than X^{-} ,
- A student must make a buffer solution with a pH of 3.5. Determine which of the acids and conjugate bases listed below are the best options to make a buffer at the specified pH. \\ Weak acids: \\ A. \text{ formic acid, } K_a = 1.77 \times 10^{-4},\ 2.00\
- A buffer consists of 0.14 M KHCO3 and 0.61 M K2CO3. Carbonic acid is a dirpotic acid with Ka1 = 4.5 times 10^(-7) and Ka2 = 4.7 times 10^(-11). A) Which Ka value is more important to this buffer? B) W
- An aqueous solution of CH3NH3NO3 will be : - basic, because of the hydrolysis of NO3^- ions. - acidic, because of the hydrolysis of CH3NH3^+ ions. - basic, because of the ionization of CH3NH2. - basic, because of the hydrolysis of CH3NH3^+ ions. - aci
- If an acid has a Ka of 1.9 x 10-3, what is the Kb for its conjugate base?
- Which of the following acids (listed with K_a values) and their conjugate base would form a buffer with a pH of 2.34? a. HC_7H_5O_2, K_a = 6.5 times 10^-5. b. HF, K_a = 3.5 times 10^-4. c. HClO, K_a = 2.9 times 10^-8. d. HCN, K_a = 4.9 times 10^-10. e. HC
- Design a buffer that has a pH of 5.58 using one of the weak base/conjugate acid systems shown below. Weak Base Kb Conjugate Acid Ka pKa CH3NH2
- A weak base has Kb = 1.5 x 10-9. What is the value of Ka for the conjugate acid?
- The value of Ka for phenol (a weak acid) is 1.00 times 10-10. What is the value of Kb for its conjugate base, C6H5O-?
- The value of Ka for phenol (a weak acid) is 1.00 x 10-10. What is the value of Kb for its conjugate base, C6H5O-?
- Write the conjugate acid/base for the following dissociating in water. i. HCOOH (acid). ii. HONH_2 (base).
- If the K_a of the conjugate acid is 2.66 times 10^{-8}, what is the pK_b for the base?
- Which of the following acids is best suited for preparing a buffer solution with pH = 3.7 and a high buffer capacity? (a) HNO_2 (b) HClO (c) HCOOH (d) HClO_2.
- H2CO3 and HCO3- are used to create a buffer solution. When an acid is introduced into this buffer, which of H2CO3 and HCO3- reacts with the acid to maintain the pH of the solution?
- A buffer solution is one that contains: a) a weak acid and its conjugate base. b) strong base and its conjugate acid. c) strong acid and its conjugate base. d) none of these.
- Design a buffer that has a pH of 5.70 using one of the weak base/conjugate acid systems shown below. Weak Base Kb Conjugate Acid Ka pKa CH3NH2 4.2 10-4 CH3NH3+ 2.4 10-11 10.62 C6H15O3N 5.9 10-7 C6H1
- The value of Ka for hypochlorous acid is 3.50 x 10-8. What is the value of Kb for its conjugate base, ClO-?
- A solution contains a mixture of 0.020 M of a weak acid and 0.100 M of its conjugate base. The pH of the resulting solution is 5.20. What is the pKa of the weak acid?
- A buffer solution could be formed when a solution of methylamine, CH3NH2, is mixed with a solution of: a. CH3OH b. KOH c. HI d. NaCl e. (CH3)2NH
- What is the H3O+ of a buffer that consists of 0.27 M HNO2 and 0.71 M KNO2? (Ka of HNO2 = 7.1 x 10-4)
- Aqueous solution of Na2CO3 is alkaline because: a) it is basic in nature. b) it is acidic in nature. c) of its anionic hydrolysis of salt of strong acid and strong base. d) of its anionic hydrolysis of salt of weak acid and strong base.
- Write the formula for the conjugate acid of each of the following bases. Base: Conjugate acid: HS- HCO3- CO32- HPO42 -SO42-
- H3PO4 has three acidic protons with the following Ka values: Ka1 = 7.1 x 10^{-3} Ka2 = 6.3 x 10^{-8} Ka3 = 4.5 x 10^{-13} If you have this acid in a solution with a pH=5 what is the predominate form of the compound in solution?
- student must make a buffer solution with a pH of 3.0. Determine which of the acids and conjugate bases listed below are the best options to make a buffer at the specified pH. Weak acids: phosphoric
- Carbonic acid dissociated into its conjugate base with K_a of 4.3 times 10^{-7}. Write the reaction of dissociation of carbonic acid in water.
- 1. A student must make a buffer solution with a pH of 5.5. Determine which of the acids and conjugate base listed below are the best options to make a buffer at the specified pH. Weak acids: - formi
- Give the conjugate base for each compound below. Acid Conjugate Base H_2S H_2PO_4^- NH_4^+
- What is the conjugate base of HF in a water solution (an aqueous solution)? 1. H^+ \\2. H_2O \\3. H_2 \\4. F^- \\5. OH
- Prepare a buffer by acid-base reactions. Consider how to prepare a buffer solution with pH = 7.23 (using one of the weak acid/conjugate base systems shown here) by combining 1.00 L of a 0.483 M solution of weak acid with 0.399 M potassium hydroxide. W e
- Consider 0.10 M solutions of the conjugate bases of each of the following acids. Which will be the strongest base? The conjugate base of: a. hypobromous acid b. acetic acid c. formic acid d. phenol e. none of the conjugate bases will have any basic behavi
- The pH of an aqueous solution of 0.340 M methylamine (a weak base with the formula CH_3NH_2) is _____.
- Consider a buffer solution whose acid component is acetic acid, CH3COOH. (a) What is a conjugate base component of this buffer? (b) Write the reaction that takes place when a small amount of OH- is introduced to this buffer solution. (c) Write the reactio
- A 0.11 M solution of a weak base A^- reacts with H_2O such that at equilibrium 99.4% of the compound remains in the A^- form. Given this information, what is the pK_a of the conjugate acid HA? Enter y
- Which weak acid would be best to use when preparing a buffer solution with a pH of 8.50? 1) an acid with Ka = 3.3 x 10^{-9} 2) an acid with Ka = 5.0 x 10^{-4} 3) an acid with Ka = 6.3 x 10^{-6} 4)
- Which weak acid would be best to use when preparing a buffer solution with a pH of 9.30? a. An acid with Ka = 3.2 x 10^-11 b. An acid with Ka = 7.9 x 10^-5 c. An acid with Ka = 5.2 x 10^-10 d.
- If the K_a of the conjugate acid is 6.99 times 10^{-7}, what is the pK_b for the base?
- Carbonic acid reacts with water to yield bicarbonate ions and hydronium ions. H2CO3 + H2O arrow HCO3- + H3O+ Identify the conjugate acid-base pairs as acid, base, conjugate acid, or conjugate base.
- 1. Identify the Bronsted-Lowry acid, conjugate base, base and conjugate acid: H3O^+ (aq) + HSO4^- (aq) doubleheadarrow H2SO4(aq) + H2O(l) 2. The OH^- concentration in a 2.5 times 10^-4 M HI solution i
- (a) What is the conjugate acid of HCO_3? enter formula: ................. (b) What is the conjugate base of HCOOH? enter the formula: ............... (c) Identify the acid, base, conjugate acid, and conjugate base in the following reaction: HS^-
- The Ka values for several weak acids are given below. Which acid (and its conjugate base) would be the best buffer at pH 3.7? ...
- Part A CH_3NH_2 (aq) + H_2O(l) right left harpoons CH_3NH_3^+ (aq) + OH^-(aq) a. acid CH_3NH_2 and base H_2O; conjugate base CH_3NH_3^+ and conjugate acid OH^-
- What is (H3O+) in a solution of 0.075 M HNO2 and 0.030 M NaNO2?
- Nitrous acid, HNO_2, has a Ka of 4.00 x 10^(-3). Give the formula for the conjugate base of HNO_2 and give the value of Kb for that conjugate base.
- 1. A buffer contains KCN and another substance. What is the formula of the other substance? 2.What is the conjugate acid of HSO4-1? 3.When HBr reacts with barium hydroxide, what is the coefficient o
- When the concentration of the conjugate base of a weak acid is equal to the concentration of the weak acid in a buffer solution, the pH of the solution is A. less than the pK_a B. greater than the pK_a C. equal to the pK_a D. always acidic E. always basic
- The value of Ka for hypochlorous acid is 3.50 times 10-8. What is the value of Kb for its conjugate base, ClO-?
- Buffers are formed by making solutions containing a weak acid and the salt of its conjugate base or solutions of a weak base and the salt of its conjugate acid. However, buffers cannot be formed by if
- Phenol (C6H5OH), commonly called carbonic acid, is a weak organic acid. C6H5OH(aq) + H2O(l) arrow C6H5O-(aq) + H3O+(aq); Ka = 1.3 x 10-10 If you dissolve 0.876 grams of the acid in enough water to make 137 mL of solution, what is the equilibrium hydronium
- What is the conjugate acid of the hydroxide ion? a. H3O+ b. OH- c. H3O d. OH e. H2O
- Consider a buffer solution where conjugate base greater than weak acid, how is pH related to pKa?
- The compound methylamine is a weak base like ammonia. A solution contains 0.152 M CH3NH3+ and 0.296 M methylamine, CH3NH2. What is the pH of this solution?
- You have two buffer solutions: 1) weak acid and its conjugate base 2) weak base and its conjugate acid. Write explicitly (considering generic formula for acid and base) the equations of neutralization
- When an acid is added to a buffer composed of HNO2 and NaNO2, the H3O+ is neutralized by? A) NO2- B) HNO2 C) Water
- Hydrogen cyanide (HCN) is a Bronsted acid. Write the balanced reaction for its dissolution in water, and label the acid, base, conjugate acid, and conjugate base.
- Which is equal to the pKa of a weak acid? a) the equilibrium concentration of conjugate base b) the pKa of its conjugate acid c) the pH of a solution containing equal amounts of the weak base d) its relative molecular mass
- The substance nitrous acid, HNO2, is a weak acid (Ka = 4.6 x 10-4). What is the value of Kb for its conjugate base, the NO2- ion?
- If the dissociation constant of a weak acid is 7.9 x 10-5, at what ratio should you adjust the concentration of the weak acid and its conjugate base in order to prepare a buffer that has a pH of 4.10? a. 0.0100 M weak acid with 0.100 M conjugate base b. 0
- A 0.20 M solution of a weak base A- reacts with H2O such that at equilibrium, 99.4% of the compound remains in the A- form. Given this information, what is the pKa of the conjugate acid HA?