A 55 gallon drum of waste water contains chromium waste from an electroplating business. The...
Question:
A 55 gallon drum of waste water contains chromium waste from an electroplating business. The standard for chromium in drinking water is 100 ppb (0.1 mg/L) The chromium waste is in the form of dichromate ion (Cr2O7{eq}^{2-} {/eq}) in a solution of strong sulfuric acid. If the drum of waste water contains 1.5 ounces of K2Cr2O7 (potassium dichromate,) calculate the dilution required to lower the concentration of chromium ions (Cr{eq}^{6+} {/eq}) to the permissible level for drinking water. (don't panic if your number looks really big - like huge!)
Dilution:
An experimental setup often needs to change the solution concentration by creating modifications to the amount of solvent. This process is known as dilution which describes the method of decreasing the solute concentration in the mixture. This can be mathematically shown in the equation
$$\rm{C_1V_1=C_2V_2}$$
Answer and Explanation: 1
Become a Study.com member to unlock this answer! Create your account
View this answer
First, we will determine the concentration of {eq}Cr^{6+}{/eq} in the drum of wastewater. Note that 1 ounce is equal to 28.3495 g and 1 gallon is...
See full answer below.
Ask a question
Our experts can answer your tough homework and study questions.
Ask a question Ask a questionSearch Answers
Learn more about this topic:

from
Chapter 8 / Lesson 5Want to know how to calculate dilution factor? See dilution equations, the dilution formula, and learn how to dilute acid and how to dilute a solution.
Related to this Question
- The concentration of potassium dichromate in waste water is found to be 4.85 \times 10^{-7} M. Calculate the ppm (parts per million; mg/L) of chromium (VI) present in the waste water.
- a)What mass of chromium is present in 234 grams of an ore of chromium that is 55.0 % iron(II) dichromate, FeCr_2O_7, and 45.0 % impurities by mass? b) If 90.0 % of chromium can be recovered from 400 grams of the ore, what mass of pure chromium is obtained
- Stainless steel is an alloy of iron, chromium, and nickel, having approximately 15.5% chromium. In an assay to discover how much chromium is present, the steel is oxidize in acid to form chromate ion. The resulting solution is treated with excess lead(II)
- A standard K_2Cr_2O_7 solution was first prepared by dissolving 1.2275 grams of previously dried potassium dichromate with deionized water in a 250 mL volumetric flask and diluting to the mark with deionized water. A 2.4234-gram sample of the iron (II) co
- All of the chromium in a 0.750 gram sample of ore is converted to K_2CrO_4. The K_2CrO_4 is dissolved in acid and the CrO_4^{-2} (aq) is titrated with a 0.0200 M solution containing Sn^{+2} ions. The skeleton reaction is below. CrO_4^{-2} + Sn^{+2} right
- What is the correct disposal for titrated mixture of HCl, Na_2CO_3 and water solution a. In the sink/drain. b. In the hazardous waste bottle provided by the instructor/TA. c. In trash.
- An 8.75-g sample of iron ore (mixture) is transformed to a solution of iron(II) sulfate, and this solution is titrated with 0.150 M K2Cr2O7 potassium dichromate. If it requires 67.8 mL of potassium dichromate solution to titrate the iron(II) sulfate solut
- A car bumper is plated with chromium using chromium (III) ions in a solution. If a current of 54 A flows in the cell for 45 min 30 s, determine the mass of chromium deposited on the bumper.
- Chromium (III) oxide, often called chromic oxide, has been used as green paint pigment, as a catylistin organic synthesis, as a polishing powder, and to make metallic chromium. One way to make chromium (III) oxide is by reacting sodium dichromate, Na_2Cr_
- A 3.75-g sample of iron ore is transformed to a solution of iron(II) sulfate, FeSO4, and this solution is titrated with 0.150 M K2Cr2O7 (potassium dichromate). If it requires 43.7 mL of potassium dichromate solution to titrate the iron(II) sulfate solutio
- A 3.33 g sample of iron ore is transformed into a solution of iron (II) sulfate. This solution is titrated with 0.0150 M potassium dichromate. If it requires 41.40 mL potassium dichromate solution to
- Chromium is an essential nutrient, but too much of it can be toxic. Current EPA guidelines put the maximum chromium content in drinking water to 100.0 ppb. Nutritionists suggest that we drink eight 8-ounce glasses of water per day. Assuming the upper limi
- Chromium and candmium can be removed from wastewater by treatment with sodium hydroxide. Show the net ionic reactions of Cr^3+(aq) snd Cd^2+(aq) with NaOH(aq) Cr3^+(aq) reacts with NaOH(aq) Cd^2+(aq)
- Most of the chemicals included in the General Chemistry Lab kit can be discarded down a drain. Describe a situation in which you would need to neutralize any chemical before discarding down a drain.
- Sulfuric acid + sodium carbonate solution CME CIE NIE Sulfuric acid + ammonia solution CME CIE NIE Rubidium metal + water CME CIE NIE Copper metal + iron(ll) sulfate solution CME CIE NIE S
- A sample of a chromium-containing alloy weighing 3.450 g was dissolved in acid, and all the chromium in the sample was oxidized to 2CrO4^2-. It was then found that 3.18 g of Na2SO3 was required to reduce the 2CrO4^2- to CrO2^- in a basic solution, with th
- A solution of K2Cr2O7 is standardized against Fe(NH4)2(SO4)2 6H20. Exactly 0.625 g of the iron salt is equivalent to 22.5 mL of the dichromate solution. A sample of unknown iron (II) is then titrated with the dichromate. Exactly 25.0 mL of the iron is equ
- Indicate the proper waste container for a solution of sodium chloride and water. a. non-halogenated organic waste b. halogenated organic waste c. aqueous waste d. trash can e. glass waste box
- Waste water from certain industrial chemical processes contains aqueous Hg_2^{2+} ions. Since the mercury ion is toxic, it is removed from the waste water by reaction with aqueous sodium sulfide. The products of the reaction are solid mercury(I) sulfide a
- A silver recovery unit can process 1500 L of photographic silver waste solution per day. Adding excess solid sodium chloride to a 500 mL sample of the waste gives a white precipitate that, after filtration and drying, consists of 3.73 g of AgCl. a. Write
- Selenium in 10.0 g of a soil sample is extracted as selenium trioxide ion, which is determined iodometrically requiring 4.5 mL of thiosulfate. If the thiosulfate reacts with a dichromate solution 0.049 mg K_2Cr_2O_7 / mL, What is the concentration of Se i
- A solution is prepared by dissolving 11.3 g of a mixture of sodium carbonate and sodium bicarbonate in 1.00 L of water. A 300.0 cm3 sample of the solution is then treated with excess HNO3 and boiled t
- A solution is prepared by dissolving 11.60 g of a mixture of sodium carbonate and sodium bicarbonate in 1.00 L of water. A 300.0-cm^3 sample of the solution is then treated with excess HNO_3 and boiled to remove all the dissolved gas. A total of 0.952 L o
- A strip of chromium is placed in a 1 M solution of chromium (III) sulfate, and a strip of copper is placed in a 1 M solution of copper (II) chloride. The two solutions are connected with a salt bridge, and the two metals are connected by a wire. Reductio
- A strip of chromium is placed in a 1 M solution of chromium (III) sulfate, and a strip of copper is placed in a 1 M solution of copper (II) chloride. The two solutions are connected with a salt bridge, and the two metals are connected by a wire. R e d u
- A solution containing hazardous waste is charged into a storage tank and subjected to a chemical treatment that decomposes the waste to harmless products. The concentration of the decomposing waste, C
- A solution is prepared by dissolving 11.6 g of a mixture of sodium carbonate and sodium bicarbonate in 1.00 L of water. A 300.0 cm3sample of the solution is then treated with excess HNO3 and boiled to
- Purification of chromium can be achieved by electrorefining chromium from an impure chromium anode onto a pure chromium cathode in an electrolytic cell. How many hours will it take to plate 17.5 kg of
- Purification of chromium can be achieved by electrorefining chromium from an impure chromium anode onto a pure chromium cathode in an electrolytic cell How many hours will it take to plate 10.5 kg of
- A 1.317 g sample of a metal carbonate (MCO_3) was treated with 100.00 mL of .1083 M sulfuric acid (H_2SO_4), yielding CO_2 gas and an aqueous solution of the metal sulfate ((MS)_4). The solution was boiled to remove all the dissolved CO_2 and was then tit
- A student did not rinse the volumetric flask out after preparing the standard nickel ion solution. The student used the same volumetric flask to prepare the solution of the unknown nickel ion. How wil
- Limonite is an ore of iron that contains 2Fe_2O_3.3H_2O. A 0.5166-g sample of limonite is dissolved in acid and treated so that all the iron is converted to ferrous ions, Fe^(2+). This sample requires 42.96 mL of 0.02130 M sodium dichromate solution, Na_2
- True or false? Chromium metal can dissolve in dilute HCl.
- The iron content of iron ore can be determined by titration with a standard KMnO4 solution. The iron ore is dissolved in HCl, and all the iron is reduced to Fe2+ ions. This solution is then titrated with KMnO4 solution, producing Fe3+ and Mn2+ ions in
- A sample of 1.55 g of iron ore is dissolved in a acid solution in which the iron is converted into Fe^{2+}. The solution formed is then titrated with KMnO_4 which oxidises Fe^{2+} to Fe^{3+} while the
- A 0.4407 g sample of pewter, (containing tin, lead, copper and zinc) was dissolved in acid, tin was precipitated as SnO2 4H2O and removed by filtration. The resulting filtrate and Washington were dilu
- Chlor-alkali plants electrolyze NaCl to produce the commodity chemicals caustic soda and chlorine gas. Industrial waste effluent released into waterways from these plants can contain trace amounts of mercury. Legally, the effluent can contain up to 2.50 \
- Saccharin (C7H5NO3S) is sometimes dispensed in tablet form. Ten tablets with a total mass of 0.5797 g were dissolved in water. The solution was then oxidized to convert all the sulfur to sulfate ion,
- Austenitic steel is composed of 74% iron, 18% chromium and 8% nickel. Which of the following can be called the solute(s)? a. Chromium alone b. Chromium and nickel c. Chromium and iron d. Iron and nickel e. Nickel alone
- A student cleaned a crucible with HCl. After pouring the HCl into the waste container, the crucible was neither rinsed with water or dried before the student added the NaHCO_3 and KCl mixture. The cru
- 2. Fill the cuvettes with the following amounts of 0.06 M copper (II) sulfate solution and 1.0 M nitric acid (HNO3):
- In the analysis of an ore sample for Ni using an acidic dichromate solution, 0.04256 liters of dichromate titrant were required. If the sample contained exactly 2.5000 grams of ore, the final oxidatio
- A sample weighing 0.0123 g was dissolved in concentrated nitric acid to convert all of the arsenic to arsenate. The solution was diluted 10 times and excess silver added to precipitate silver arsenate (Ag_3 \cdot AsO_4), which was collected, dried, and we
- A sample of lead ore was analyzed for lead content by dissolving 4.9770 g of the ore in sulfuric acid solution. The resultant reaction produced a precipitant of lead sulfate, which was isolated by filtering, washing, and drying. If 0.5823 g of lead sulfat
- Indicate the proper waste container for a mixture of biphenyl and benzoic acid in ethanol. a. non-halogenated organic waste b. halogenated organic waste c. aqueous waste d. trash can e. glass waste box
- A 0.4436 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO2 4H2O and removed by filtration. The resulting filtrate and washings were dilute
- A 0.4423 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO2 4H2O and removed by filtration. The resulting filtrate and washings were dilute
- A 0.4718 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO2 4H2O and removed by filtration. The resulting filtrate and washings were dilute
- A 0.4858 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO2 4H2O and removed by filtration. The resulting filtrate and washings were dilute
- The iron content of iron ore can be determined by titration with a standard KMnO4 solution. The iron ore is dissolved in HCl, and all the iron is reduced to Fe^2+ ions. This solution is then titrated with a KMnO4 solution, producing Fe^3+ and Mn^2+ ions i
- Saccharin (C7H5NO3S) is sometimes dispensed in tablet form. Ten tablets with a total mass of 0.5860 g were dissolved in water. They were oxidized to convert all the sulfur to sulfate ion, which was pr
- Saccharin (C7H5NO3S) is sometimes dispensed in tablet form. Ten tablets with a total mass of 0.5894 g were dissolved in water. This solution was then oxidized to convert all the sulfur to sulfate ion, which was precipitated by adding an excess of barium
- The sodium sulfite-acid solution should be disposed of by: 1) washing down the drain with large amounts of water. 2) washing out with diluted sodium bicarbonate for sink disposal. 3) neutralizing t
- Chromium plating is done using a dichromate solution. How long would it take to plate 1.0 times 10^{-2} mm thick onto a car bumper with surface area 0.25 m^2 in a 25.0 Amp electrolytic cell? (Density
- Zinc ore (zinc sulfide) is treated with sulfuric acid, leaving a solution with some undissolved bits of material and releasing hydrogen sulfide gas. If 10.8 g of zinc ore is treated with 50.0 mL of sulfuric acid (density 1.153 g/mL), 65.1 g of solution an
- If you put pure zinc metal into a solution of copper (II) sulfate, the zinc will slowly dissolve to produce a zinc sulfate solution, and the copper (II) ion of the copper (II) sulfate will be converte
- After completing an experiment, all hazardous chemical waste should be: a) disposed of in the sink. b) disposed of in the trash. c) disposed of in the appropriate waste container. d) left in the lab.
- On the TV show Breaking Bad, an acid was attempted to be used to dispose of a body in a metal bathtub. However, the bathtub dissolved in the process. Many acids react in a redox reaction with metals to form H2 gas, resulting in the dissolution of the meta
- The drinking water problems in Flint, Michigan stem from the loss/damage to the passivation layer on the inside of the water delivery pipes due to the failure to add this chemical class of corrosion inhibitor to the water. (a) sulfate (b) nitrate (c) carb
- A solution of potassium permanganate (KMnO_4) was standardized by titrating with 0.1908 g of Na_2C_2O_4 dissolved in 50 cm^3 of acidified water. The endpoint was reached after 24.50 cm^3 of the soluti
- A 0.5412 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO_2 4H_2O and removed by filtration. The resulting filtrate and washings were dilu
- Magnetite is a mineral having the formula Fe3O4 or FeOFe2O3. A 1.1324-g sample of a magnetite ore was dissolved in concentrated HCl to give a solution that contained a mixture of Fe^{2+} and Fe^{3+}. Nitric acid was added and the solution was boiled for a
- 0.521g of brass were dissolved in concentrated nitric acid, diluted with distilled water to 50.0ml in a volumetric flask, filtered, and found to have a Cu2+ molarity of 0.0931mole/liter. The percent copper in this sample was then calculated. if a student
- Saccharin (C7H5NO3S) is sometimes dispensed in tablet form. Ten tablets with a total mass of 0.5800 g were dissolved in water. They were oxidized to convert all the sulfur to sulfate ion, which was pr
- In the standardization of potassium permanganate. 1) Why is is unnecessary to add an indicator during the titration? 2) Why is the solution of sodium oxalate acidified with sulfuric acid before titration? 3) Why is the solution of sodium oxalate heated to
- One way in which the useful metal copper is produced is by dissolving the mineral azurite, which contains copper(II) carbonate, in concentrated sulfuric acid. The sulfuric acid reacts with the copper(
- A solution of potassium permanganate is standardized with iron metal, a primary standard. The iron is dissolved in acid, reduced to Fe(II), and titrated with permanganate. 5Fe^2+(aq) + MnO_4^-(aq) + 8H^+(aq) to 5 Fe^3+(aq) + Mn^2+ + 4H_2O(l) 33.17 mL of p
- A voltaic cell is constructed from a half-cell in which a chromium rod dips into a solution of chromium(III) nitrate, Cr(NO_3)_3, and another half-cell in which a lead rod dips into a solution of lead(II) nitrate, Pb(NO_3)_2. The two half-cells are connec
- A soft-drink bottling plant discharges a wastewater with a dissolved solids concentration of 10,000 mg/L NaCl at a rate of 100 gal/min to a stream. The stream above the discharge has a volumetric flow rate of 1.0 MGD and a dissolved solids concentration o
- Lead (II) acetate + Sulphuric acid solution CME CIE NIE Lead (II) sulfate + nitric acid solution CME CIE NIE
- In Electrochemical Series lab for the waste disposal of Copper Gluconate, the excess copper gluconate had to be safely disposed of by first plating out the copper using 2 aluminum washers.
- A sample of iron ore weighing 385.6 mg was dissolved in acid and passed through a Jones reductor. The resulting solution was 52.36 mL of 0.01436 M K2Cr2O7 for titration to the diphenylamine sulfonic a
- Austenitic steel is composed of 74% iron, 18% chromium, and 8% nickel. Which of the following can be called the solute(s)? (a) Iron and nickel (b) Iron alone (c) Chromium and iron (d) Chromium alone (e) Chromium and nickel
- The maximum level of each metal in drinking water is given below. Convert each value to parts per million. a. copper, 1,300 g/kg b. arsenic, 10 g/kg c. chromium, 100 g/kg
- A 1.268 g sample of a metal carbonate (MCO3) was treated with 100.00 mL of 0.1083 M sulfuric acid (H2SO4), yielding CO2 gas and an aqueous solution of the metal sulfate (MSO4). The solution was boiled to remove all the dissolved CO2 and was then titrated
- The chief ore of zinc is the sulfide, ZnS. The ore is concentrated by flotation and then heated in air, which converts the ZnS to ZnO. 2ZnS + 3O_2 \to 2ZnO + 2SO_2 The ZnO is then treated with dilute H_2SO_4 to produce an aqueous solution containing the
- One way in which the useful metal copper is produced is by dissolving the mineral azure, which contains copper(II) carbonate, in concentrated sulfuric acid. The sulfuric acid reacts with the copper(II
- Walter produced a liquid waste stream containing formate (HCOO^-). If he wants to get rid of the evidence biologically by aerating the waste: For a waste stream flow of 10^7 gallons/day and a concentration of 1000 mg, what is the formate-loading rate?
- The amount of iron in ore can be quantitatively determined by titrating a solution of the unknown with a standard solution of dichromate. The net ionic equation is as follows. 6Fe2+(aq) + Cr2O72-(aq) + 14H+(aq) arrow 6Fe3+(aq) + 2Cr3+(aq) + 7H2O(aq) The t
- In one analysis, a 1.00 g sample containing sodium oxalate was first dissolved in acid to form oxalic acid. Then, the solution was titrated with a standard 0.100 M potassium permanganate, KMnO_4, solu
- Standardized potassium permanganate solutions are often used as the oxidizing agent in titrations. They are often standardized by titrating weighed out amounts of sodium oxalate. The products in acidic solution are manganese(II) and carbon dioxide. Write
- An 8.00 g sample of an iron ore was dissolved in an acid solution and the iron converted to the +2 oxidation state. The resulting solution took 75.0 mL of 0.200 M KMnO_4 solution to titrate to a light pink color.
- Crystalline perchloic acid monohydrate is to be added to a water to give a concentration of 2.0 mg/L. If water is to be supplied at a rate of 15 Million gallons a day, how many pounds of crystalline perchloric acid monohydrate will be required per day?
- A 0.4543 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO2 4H2O and removed by filtration. The resulting filtrate and washings were dilu
- A 0.4467 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO_2 4H_2O and removed by filtration. The resulting filtrate and washings were dil
- A 0.4684 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO_2 4H_2O and removed by filtration. The resulting filtrate and washings were di
- A 0.4676 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as.SnO_2 4H_2O and removed by filtration. The resulting filtrate and washings were di
- Calcium oxalate (CaC2O4) is insoluble in water. For this reason it can be used to determine the amount of Ca^{2+} ions in fluids such as blood. The calcium oxalate isolated from blood is dissolved in acid and titrated against a standardized KMnO4 solution
- A chemistry student adds a quantity of an unknown solid compound X to 5.00 L of distilled water at 15 degrees Celsius. After 10 minutes of stirring, only a little X has dissolved. The student then drains off the solution and evaporates the water under vac
- What is the proper way to dispose of solid and liquid waste containing silver? Select one or more: a. out the window b. specified waste receptacle in fume hood c. in the garbage d. down the sink drain
- A 1.268 g sample of a metal carbonate (MCO3) was treated with 100.00 mL of 0.1083 M sulfuric acid (H2SO4), yielding CO2 gas and an aqueous solution of the metal sulfate (MSO4). The solution was boiled to remove all the dissolved CO2 and was then titrate